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Synthesis of Double and Quadruple Butterfly Fe/S Cluster Complexes via a Novel Type of Reaction of Anions (μ-RS)(μ-S - )[Fe 2 (CO) 6 ] 2 (μ 4 -S) with Succinyl Chloride

✍ Scribed by Song, Li-Cheng; Lu, Guo-Liang; Hu, Qing-Mei; Sun, Jie

Book ID
126870764
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
75 KB
Volume
18
Category
Article
ISSN
0276-7333

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Synthesis and Characterization of Double
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Synthesis of Double and Quadruple Butterfly Fe/E Cluster Complexes via a New Type of Selenium-Centered Anions ( μ -RE)( μ -Se - )[Fe 2 (CO) 6 ] 2 ( μ 4 -Se) (E = S, Se, Te) Derived from Novel Reaction of [( μ -RE)( μ -CO)[Fe 2 (CO) 6 ] - with ( μ -Se 2 )Fe 2 (CO) 6 . Crystal Structures of μ 4 -Se-Containing Double Clusters ( μ -EtS)( μ -PhCH 2 Se)[Fe 2 (CO) 6 ] 2 ( μ 4 -Se), ( μ - p -MeC 6 H 4 Se)( μ -MeSe)[Fe 2 (CO) 6 ] 2 ( μ 4 -Se), and ( μ - p -MeC 6 H 4 Te)( μ
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