Synthesis of dl-3,3,4-Trimethylcyclopentanone
β Scribed by Baumgarten, Henry E.; Gleason, Donald C.
- Book ID
- 127278694
- Publisher
- American Chemical Society
- Year
- 1951
- Tongue
- English
- Weight
- 861 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
The chemical synthesis of racemic diacyloxypropylphosphonylcholines having octanoyl, myristoyl, oleoyl and stearoyl groups is described. The route involved reaction of dioactanoyloxy-, dimyristoyloxy-, dioleoyloxy-, and distearoyloxypropyliodide with tris(trimethylsilyl) phosphite to yield {he corre
3-Deoxy-DL-prumycin (1) was synthesized from 2-furanmethanol (2-furfuryl alcohol, 2) in eleven steps in 15% total yield. Michael addition of azide anion to 2,3-dideoxy-oqent-2-enopyranos~ulose (3) and reduction in situ of the adduct afforded the key intermediates 5 and 6. Introduction of a second ax