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Synthesis of Diterpene Indoles from Cyclopentenonepimaric Acid

✍ Scribed by E. V. Tret'yakova; O. B. Flekhter; F. Z. Galin; L. V. Spirikhin; G. A. Tolstikov

Book ID
110395662
Publisher
Springer
Year
2002
Tongue
English
Weight
25 KB
Volume
38
Category
Article
ISSN
0009-3130

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## Abstract An efficient, stereocontrolled total synthesis of the complex indole‐diterpene alkaloid (βˆ’)‐21‐isopentenylpaxilline (**1**) has been achieved. Key elements of the synthesis include the stereocontrolled construction of the advanced eastern hemisphere (βˆ’)‐**68**, involving a highly effici