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Synthesis of Dineopentyl Phosphorothiocyanatidate: The First Compound with the Structure

✍ Scribed by Dipl.-Chem. Andrzej Łopusiński; Prof. Dr. Jan Michalski


Publisher
John Wiley and Sons
Year
1972
Tongue
English
Weight
120 KB
Volume
11
Category
Article
ISSN
0044-8249

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This paper presents two methods for the synthesis of the first reaction of [(Me 3 Si) 2 NB(C 5 H 5 ) 2 ], prepared in situ, with Ti(NMe 2 ) 4 and converted into the chloro derivatives [1]boratitanocenophanes. The novel biscyclopentadienylborane [(Me 3 Si) 2 NB(C 5 H 5 ) 2 ], the dilithio salt Li 2 [