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Synthesis of (±)-dihydroxyserrulatic acid via (arene)chromium complexes

✍ Scribed by Motokazu Uemura; Hikaru Nishimura; Yuji Hayashi


Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
238 KB
Volume
31
Category
Article
ISSN
0040-4039

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Synthesis of axially chiral benzamides u
✍ Hiroshige Koide; Motokazu Uemura 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 175 KB 👁 1 views

Axially chiral N,N-diethyl 2,6-disubstituted benzamides were stereo-selectively prepared utilizing planar chiral (arene)chromium complexes as an enantiomerically active form by following two methods. Ortho-lithiation of the enantiomerically pure planar chiral tricarbonyl(N,N-diethyl 2-methylbenzamid