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Synthesis of dihydrophosphorins by the thermal transformation of phosphole-dichlorocarbene adducts

✍ Scribed by Keglevich, Gyorgy; Androsits, Beata; Toke, Laszlo


Book ID
127332464
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
442 KB
Volume
53
Category
Article
ISSN
0022-3263

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## Abstract Dichlorocarbene, generated from base‐catalysed decomposition of chloroform, adds to the double bond of 2‐methylisoquinolin‐1‐one (**1**), to give the 1:1 adduct (**2**). The latter adduct reacts with water to give __E__‐3‐(formylmethylene)‐2‐methylisoindolinone (**3a**). Refluxing of **