Synthesis of dihydro-10H-pyrano[3′,4′: 5,6]pyrido[3,2:4″,5″]-thieno[3″,2″-d][3,1]oxazines and pyrimidines
✍ Scribed by V. V. Dabaeva; A. S. Noravyan; B. D. Enokyan
- Publisher
- Springer US
- Year
- 1995
- Tongue
- English
- Weight
- 307 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0009-3122
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## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract magnified image The cyclocondensation of 5‐hydroxy‐pyrido[2,3‐__d__]pyrimidines **1** with malonates gives pyrano[2′,3′:4,5]‐pyrido[2,3‐__d__]pyrimidines **2**. Nitration of **1** and reduction with zinc in the presence of carboxylic acids/anhydrides gave 2‐alkyloxazolo[5′,4′:4,5]pyrid
## Abstract magnified image The thienopyridine derivative **2**, obtained from reaction of acetoacetic ester with **1** in the presence of tin tetrachloride, was treated with triphenylphosphine in hexachloroethane and Et~3~N to give iminophosphorane **3**. Iminophosphorane **3** reacted with pheny