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Synthesis of diaryl ethers through the copper-catalyzed arylation of phenols with aryl halides using microwave heating

✍ Scribed by Huan He; Yong-Jin Wu

Book ID
104253492
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
132 KB
Volume
44
Category
Article
ISSN
0040-4039

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✦ Synopsis

The copper-catalyzed arylation of phenols with a variety of aryl halides using microwave heating is described.

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Diaryl ethers are readily synthesized in high yield at room temperature through the copper(II)-prorooted coupling of arylboronic acids and phenols. The reaction is tolerant of a wide range of substituents on both coupling partners. These reaction conditions permit the racemization-free arylation of