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Synthesis of derivatives of 2-imino-5,6-dihydro-2H-thiopyran from 1-heteroalkyl-1,3-butadienes and isothiocyanates

✍ Scribed by Nina A Nedolya; Lambert Brandsma; Hermann D Verkruijsse; Anca H.T.M van der Kerk; Boris A Trofimov

Book ID: 104258755
Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 154 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)86431-3

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✦ Synopsis

A number of derivatives of 2-imino-5,6-dihydi'o-2H-thiopyran have been obtained in fair to good yields by treating the adducts from the a-metallat~dienes H2CffiCH-CH--C(M)X (X ffi OCH 3 tr SCH 3) and isotbioeyanates wi~ a calculated amount of dilute acid.

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