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Synthesis of deepoxy-4,5-didehydromethylenomycin a and methylenomycin a methyl esters

✍ Scribed by C. Mahidol; C. Thebtaranonth; Y. Thebtaranonth; C. Yenjai

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 208 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)80677-8

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✦ Synopsis

methyl ester 9 are synthesized from anthracene aclduct 2 via a common intermediate 13 Flash vacuum pyrolysis of adduct 13 gives 8 , while stereospecific epoxidation of 13 followed by pyrolysis yields 9 .

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