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Synthesis of decalin synthons of bioactive terpenoids: Lewis acid catalyzed Diels-Alder reactions

โœ Scribed by T. Mayelvaganan; Shreeshailkumar B. Hadimani; Sujata V. Bhat

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
189 KB
Volume
53
Category
Article
ISSN
0040-4020

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โœฆ Synopsis

Diels-Alder reaction of 1,3,3-trimethyl-2-vinylcyclohexene I with conjugated ketones 2 -7 in the presence of Lewis acid leads to regto-and stereo-selective formation of bicyclic adducts 8 -13 versatile intermediates to labdanes, abietane and spongian diterpenoids.

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