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Synthesis of Deacetoxycephalosporin S-Oxides by Oxidative Trapping of Sulfenic Acids from Penicillin S-Oxides

✍ Scribed by Dr. Stjepan Kukolja; S. R. Lammert

Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
250 KB
Volume
12
Category
Article
ISSN
0044-8249

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✍ S. Kabilan; R. Girija; V. Rajagopal πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 119 KB πŸ‘ 1 views

Kinetics of oxidation of 24 S-Arylmercaptoacetic acids (SAMA) by pyridinium chlorochromate (PCC) have been studied in acidmedium. The product of oxidation is the corresponding thiophenol. The rate data of meta-and para-substituted acids have been correlated well with I , R o values and the meta-comp