✦ LIBER ✦

Synthesis of d-arabinofuranosides using propane-1,3-diyl phosphate as the anomeric leaving group

✍ Scribed by Yuan Li; Gurdial Singh

Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 90 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)01327-2

No coin nor oath required. For personal study only.

✦ Synopsis

2%,3%,5%-Tri-O-benzyl-D-arbinofurano-1-O-propane-1,3-diylphosphate was activated with TMSOTf to afford 1-O-linked arabinofuranosides with good stereoselectivity.

📜 SIMILAR VOLUMES

ChemInform Abstract: Synthesis of D-Arab

ChemInform Abstract: Synthesis of D-Arabinofuranosides Using Propane-1,3-diyl Phosphate as the Anomeric Leaving Group.

✍ Yuan Li; Gurdial Singh 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB 👁 2 views

Synthesis of fucosidase substrates using

Synthesis of fucosidase substrates using propane-1,3-diyl phosphate as the anomeric leaving group

✍ Hariprasad Vankayalapati; Gurdial Singh 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 208 KB

Activation of the anomeric centre of suitably protected L-fucopyranose and t~-galactopyranose with propane-l,3-diyl phosphate allowed the synthesis of the disaccharide ct-L-Fucp-(1.2)-13-D-Galp(l)-4methylumbelliferone as a fucosidase substrate.

ChemInform Abstract: Stereoselective O-G

ChemInform Abstract: Stereoselective O-Glycosylation Reactions Employing Diphenylphosphinate and Propane-1,3-diyl Phosphate as Anomeric Leaving Groups.

✍ V. HARIPRASAD; G. SINGH; I. TRANOY 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

Stereoselective O-Glycosylation Reactions Employing Diphenylphosphinate and Propane-1,3-diyl Phosphate as Anomeric Leaving Groups. -Glycosidation of tetra-O-benzyl-D-glucose (I) using diphenylphosphinate as the leaving group affords β-O-linked glycosides (V) as major products. The use of propane-1,

ChemInform Abstract: Efficient Stereocon

ChemInform Abstract: Efficient Stereocontrolled Synthesis of C-Glycosides Using Glycosyl Donors Substituted by Propane 1,3-Diyl Phosphate as the Leaving Group.

✍ Gurdial Singh; Hariprasad Vankayalapati 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 37 KB 👁 2 views

ChemInform Abstract: Stereoselective Syn

ChemInform Abstract: Stereoselective Synthesis of α-L-Fucp-(1,2)- and -(1,3)-β-D-Galp(1)-4-methylumbelliferone Using Glycosyl Donor Substituted by Propane-1,3-diyl Phosphate as Leaving Group.

✍ Hariprasad Vankayalapati; Gurdial Singh 📂 Article 📅 2000 🏛 John Wiley and Sons ⚖ 29 KB 👁 1 views

ChemInform Abstract: Nucleosides and Nuc

ChemInform Abstract: Nucleosides and Nucleotides. Part 212. Practical Large-Scale Synthesis of 1-(3-C-Ethynyl-β-D-ribo-pentofuranosyl)cytosine (ECyd), a Potent Antitumor Nucleoside. Isobutyryloxy Group as an Efficient Anomeric Leaving Group in the Vorbrueggen Glycosylation Reaction.

✍ Makoto Nomura; Tsutomu Sato; Masato Washinosu; Motoaki Tanaka; Tetsuji Asao; Sat 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 39 KB 👁 1 views