## Abstract The __N__‐silylated methyl 2‐aminocyclopropanecarboxylate 1 can be incorporated into a dipeptide via a CsF‐mediated condensation reaction with __N__‐tosylated phenylalanine chloride 5. Due to its instability the corresponding free β‐amino acid 4 could not be isolated up to now, and pept
✦ LIBER ✦
Synthesis of cyclopropyl and cyclopropenyl ethers
✍ Scribed by R.A. Olofson; Kenneth D. Lotts; Gary N. Barber
- Book ID
- 108382135
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- French
- Weight
- 249 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0040-4039
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is removed with concentrated hydrochloric acid. Distillation of the organic phase affords 13.1 g (14%) of ( 2), b.p. 31 OC/O.02 mm, yellow needles, m.p. 49 "C from methanol. It has A, , , = 295 mp, log E = 4.05 in cyclohexane, and infrared absorptions at 695 (m), 805 (s), 1000 (m), 1230 (s), and 149
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