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Synthesis of Cyclopentene Derivatives by the Cyclooligomerization of Isocyanides with Substituted Benzylidenemalononitriles.

โœ Scribed by Sergey S. Maltsev; Maxim A. Mironov; Vasiliy A. Bakulev


Publisher
John Wiley and Sons
Year
2007
Weight
17 KB
Volume
38
Category
Article
ISSN
0931-7597

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Block copolymerization of allene derivat
โœ Ikuyoshi Tomita; Masanori Taguchi; Koji Takagi; Takeshi Endo ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 733 KB

A living block copolymerization of allene derivatives with 1-phenylethyI isocyanide (3) using [(ally l) NiOCOCF~]2 ( 1 ) is described. After complete polymerization of allene monomers such as rz-octyloxyallene (2A) with 1, further addition of 3 to the reaction system yielded the corresponding block