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Synthesis of cycloocta[2,1-b:3,4-b′]diquinoline and cycloocta[2,1-b:3,4-b′]di[1,8]naphthyridine, and x-ray crystal structures of cycloocta[2,1-b:3,4-b′]diquinoline and its 2:1 complex with copper (I) perchlorate

✍ Scribed by Xiu Chun Wang; Henry N.C. Wong; Thomas C.W. Mak


Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
292 KB
Volume
28
Category
Article
ISSN
0040-4039

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✦ Synopsis


New compounds containing a diquinoline or l,L?-dinaphthyridine nucleus fused to the molecular skeleton of cyclooctatetraene have been synthesized. An X-ray analysis of cycloocta[Z,l-b:3,4_b']diquinoline (4) has revealed that the molecule contains ac 2 axis. The reaction of &with copper perchlorate furnished a complex of formula [(&)2culc104, the coordination geometry about the copper(I) atom being that of a flattened tetrahedron.


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