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Synthesis of Cyclohexanes via [3 + 3] Hexannulation of Cyclopropanes and 2-Chloromethyl Allylsilanes

โœ Scribed by Sapeta, Katarina; Kerr, Michael A.


Book ID
111900252
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
166 KB
Volume
11
Category
Article
ISSN
1523-7060

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A route to 1,2,3-trisubstituted cyclopropanes has been developed. The relative stereochemistry at the three cyclopropane centers is established by nucleophilic attack on the pentadienyl ligand on the face opposite to iron and subsequent oxidatively induced reductive elimination with retention of con