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Synthesis of cyclobutylideneacetic esters via aluminum chloride promoted [2+2] cycloadditions of ethyl 2,3-butadienoate to olefins

✍ Scribed by H.M.R. Hoffmann; Zeinhom M. Ismail; Anette Weber

Book ID: 104243992
Publisher: Elsevier Science
Year: 1981
Tongue: French
Weight: 249 KB
Volume: 22
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)92877-1

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✦ Synopsis

Summahg: In the p&esence od AJXC3, eXhgL 2,3-buhxdienaate m.ati uLith a v&&g 06 o.&iti, inc.&d&g n.&np& unaotivated cgcLoaJ?hencb, to give cgclobtigfidencactic Tim at Loom temple. The cg&oaddition 0 hcgiobc&tive and &teheoh&3dive. Cyclobutylideneacetic esters have hitherto attracted little attention, their formation having been mostly incidental in a study of the mechanism of some molecular rearrangements.

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