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Synthesis of cyclobutenone

โœ Scribed by Sieja, J. B.


Book ID
121299339
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
369 KB
Volume
93
Category
Article
ISSN
0002-7863

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Alors que l'attaque des amino-3 cyclobut6nonesApar les Grignard ne permet pas d'atteindre les cyclobutkuxres du type2 mais engendre furanne (I), d'un alcool de ce type rend, par contre. trk probable l'intervention d'un processus l-4 avec les organomagn6siens. Or en s&rie acyclique ou cyclohexenique

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In conjunction with another project it recently became necessary to develop a synthon which would be synthetically equivalent to terelactone (U1 but more reactive than 1 as a dienophile in the Diels Alder reaction. 4,4-Dimethylcyclobutenone (2) appeared to be an attractive candidate since it seemed