Synthesis of cyclic polystyrene via a combination of intramolecular coupling and ATRP
✍ Scribed by Xu Hua Shi; Hai Tao Xu; Tao Yan; Ri Wen Yu; Yin Peng Xu; Han Jia Chen
- Book ID
- 113073121
- Publisher
- Springer
- Year
- 2012
- Tongue
- English
- Weight
- 214 KB
- Volume
- 19
- Category
- Article
- ISSN
- 1022-9760
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## Abstract Mono‐ and di‐(trimethylammonium)‐terminated polystyrenes with similar molar masses were synthesized. Bromopolystyrenes were first prepared by atom transfer radical polymerization (ATRP) using (__N__‐Boc‐propylamino)‐2‐bromoisobutyrate as initiator and Cu(I)Br/2,2′‐bipyridine as catalyti
## Abstract Block copolymer synthesis via a combination of ATRP and RAFT using click chemistry is reported for the first time. A RAFT agent with a terminal propargyl group (PTTC) was synthesized and was used to polymerize butyl acrylate and gave quantitative monomer conversion. Azide‐terminated p(_
## Abstract A new well‐defined telechelic macrophotoinitiator of polystyrene was synthesized by combination of ATRP and click chemistry. The ATRP of styrene by means of 2‐oxo‐1,2‐diphenylethyl‐2‐bromopropanoate (PI‐Br) initiator with CuBr/2,2′‐bipyridine yields polystyrene with photoactive benzoin