Synthesis of cyclic poly(methyl methacrylate) by the intramolecular cyclization of α-amino, ω-carboxyl heterodifunctional poly(methyl methacrylate)
✍ Scribed by Masataka Kubo; Hisatomu Yamamoto; Takahiro Uno; Takahito Itoh; Hiroaki Sato
- Book ID
- 106002784
- Publisher
- Springer
- Year
- 2001
- Tongue
- English
- Weight
- 101 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0170-0839
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The synthesis of heterotelechelic poly(methyl methacrylate) (PMMA) containing ␣-maleimide--dienyl end-groups and its subsequent intramolecular cyclization are described. The anionic polymerization of methyl methacrylate was carried out with 3-tert-butyldimethylsilyloxypropyl-1-lithium and 5-bromo-1,
A new method of synthesizing graft copolymers having a poly(perfluoroalkylethyl methacrylate) (PFMA) backbone has been suggested and illustrated by preparing poly(perfluoroalkylethyl methacrylate)-gpoly(methyl methacrylate)s (PFMA-g-PMMA). These copolymers were prepared using the macromonomer techni