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Synthesis of cyclic enamides by intramolecular cyclization of acetylenic amides

✍ Scribed by Peter A. Jacobi; Harry L. Brielmann; Sheila I. Hauck

Publisher: Elsevier Science
Year: 1995
Tongue: French
Weight: 257 KB
Volume: 36
Category: Article
ISSN: 0040-4039
DOI: 10.1016/0040-4039(95)00031-7

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## Abstract The synthesis of several 18‐membered cyclodepsipeptides with an alternating sequence of __α,α__‐disubstituted __α__‐amino acids and __α__‐hydroxy acids (compounds **14a**–**14e**) is described. The ring closure __via__ macrolactonization was accomplished by treatment of a diluted suspen