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Synthesis of crosslinked polymers containing benzoyl peroxide groups and their use as initiators

✍ Scribed by P. Hodge; A.A. Naim

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
306 KB
Volume
25
Category
Article
ISSN
0014-3057

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✦ Synopsis

Crosslinked polystyrene beads (prepared using 2 and 20% of divinylbenzene) were chemically modified to introduce benzoyl peroxide residues in which both of the aroyl groups were attached to the polymer backbone. Using these as initiators, methyl methacrylate and N,N-dimethylacrylamide were grafted onto the beads; attempts to graft on styrene derivatives were unsuccessful.

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## Abstract **Summary:** The effects of polymerization temperature and time, initiator and monomer concentrations, ratio of water and solvent employed on the grafting of methacrylamide onto poly(ethylene terephthalate) fibers by the use of benzoyl peroxide initiator were studied. The graft yield wa