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Synthesis of copper(II) complexes of asymmetric resins prepared by attachment of α-amino acids to crosslinked polystyrene

✍ Scribed by M. A. Petit; J. Jozefonvicz


Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
465 KB
Volume
21
Category
Article
ISSN
0021-8995

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Asymmetric 1,4-Addition of Oxazolones to
✍ José Alemán; Andrea Milelli; Silvia Cabrera; Efraim Reyes; Karl Anker Jørgensen 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 322 KB

## Abstract An easy and simple synthetic approach to optically active α,α‐quaternary α‐amino acids using asymmetric organocatalysis is presented. The addition of oxazolones to nitroalkenes catalyzed by thiourea cinchona derivatives provides the corresponding α,α‐quaternary α‐amino acid derivatives