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Synthesis of contiguous cyclopropanes by palladium-catalyzed suzuki-type cross-coupling reactions

✍ Scribed by AndréB. Charette; Rossimiriam Pereira De Freitas-Gil

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
202 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis

Suzuki cross-coupling reactions between a variety of iodocyclopropanes and cyclopropylboronate esters to produce symmetrical or unsymmetrical contiguous cyclopropanes was achieved in good yields.

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Palladium-supported sepiolite clay has effectively catalyzed the Suzuki cross-coupling reaction of phenylboronic acid with aryl halide including less reactive electron-rich aryl bromides.