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Synthesis of conjugated spirocyclic polymers: Cyclopolymerization of 1,1-dipropargyl-1-silacycloalkanes by transition metal catalysts

โœ Scribed by Lee, In-Sook ;Kwak, Young-Woo ;Lee, Hak-Dong ;Gal, Yeong-Soon

Book ID
108173090
Publisher
Elsevier
Year
2008
Tongue
English
Weight
300 KB
Volume
14
Category
Article
ISSN
1226-086X

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โœ Der-Jang Liaw; Jang-Shiang Tsai ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 759 KB

The polymerization of 1-methoxy -1-ethynylcyclohexane (MEC) was carried out by various transition metal catalysts. The catalysts MoC15, MoCli, and WCIC gave a relatively low yield of polymer (< 16%). The catalytic activity of Me-based chloride catalyst was greater than that of W-based chloride catal