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Synthesis of Condensed 3-Cyanopyridin-2(1H)-ones Based on the Smiles Rearrangement

✍ Scribed by E. G. Paronikyan,A. S. Noravyan,Sh. Sh. Dashyan…

Book ID
121329479
Publisher
Springer US
Year
2013
Tongue
English
Weight
471 KB
Volume
49
Category
Article
ISSN
0009-3122

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In this Letter, we report a novel approach to the preparation of 3-anilino-pyrazin-2(1H)-ones and 3-anilino-quinoxalin-2(1H)-ones from the corresponding 3-halo pyrazin-2-amines and 3-haloquinoxalin-2-amines, using a microwave-mediated Smiles rearrangement.

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