Synthesis of compounds with juvenile hormone activity, XXVIII. Synthesis of (−)-juvenile hormone I, the antipode of the natural compound
✍ Scribed by Mori, Kenji ;Fujiwhara, Mitsuhiko
- Publisher
- John Wiley and Sons
- Year
- 1990
- Tongue
- English
- Weight
- 385 KB
- Volume
- 1990
- Category
- Article
- ISSN
- 0947-3440
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✦ Synopsis
Abstract
The synthesis of the unnatural (10__S__,11__R__)‐(−)‐juvenile hormone I [(−)‐JH I, (−)‐1] is described.
📜 SIMILAR VOLUMES
The major radiolabelled product released from ring gland and brain-ring gland complexes of third instar larval and pre-pupal stages of the sheep blowfly Lucilia cuprina upon incubation with L-[methyl-3 H]methionine corresponded to one diastereomer of juvenile hormone III bisepoxide (JHB 3 ). Endocri
dl-2-14C-Juvenile hormone was prepared from 2-1dC-trimethyl phosphonoacetate, sodium hydride and cis-9,iO-oxido-6-ethy~-iOmethy/dodec-5(t)-en-2-one in dry tetrahydrofuran and pur$ed by gas chromatography. The reaction conditions were established by synthesizing the trans-isomer of juvenile hormone.
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