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Synthesis of Chlamydocin by Chelate-Claisen Rearrangement

✍ Scribed by Christian Quirin; Uli Kazmaier

Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 203 KB
Volume: 2009
Category: Article
ISSN: 1434-193X
DOI: 10.1002/ejoc.200800890

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✦ Synopsis

Chelate-Claisen rearrangement of a chiral allylic ester allows the synthesis of the unusual epoxyketo amino acid Aoe found in chlamydocin, one representative of a group of peptidebased HDAc inhibitors.

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