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Synthesis of chiral water-soluble metalloporphyrins (Fe, Ru,): new catalysts for asymmetric carbene transfer in water

✍ Scribed by Irène Nicolas; Paul Le Maux; Gérard Simonneaux

Book ID
104095672
Publisher
Elsevier Science
Year
2008
Tongue
French
Weight
165 KB
Volume
49
Category
Article
ISSN
0040-4039

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## Abstract A new polyethylene glycol‐supported chiral monosulfonamide was synthesized from (__R__,__R__)‐1,2‐diaminocyclohexane and shown to act as a ligand for ruthenium(II)‐catalyzed asymmetric transfer hydrogenation of aromatic ketones in neat water using sodium formate as the hydrogen source.