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Synthesis of chiral sulfoxides by enantioselective sulfide oxidation and subsequent oxidative kinetic resolution using immobilized Ti–binol complex

✍ Scribed by Suman Sahoo; Pradeep Kumar; F. Lefebvre; S.B. Halligudi


Book ID
113686585
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
438 KB
Volume
262
Category
Article
ISSN
0021-9517

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## Abstract Enantioselective vanadium‐catalysed oxidation of aryl benzyl sulfides using Bolm’s procedure is accompanied by kinetic resolution in the oxidation of the resulting sulfoxides which enhances the enantiopurities of the sulfoxides recovered (typically >90 % __ee__), albeit with an associat