Optically active exo-exo-2,3-camphanediol (CPO) (3) was synthesized from (+)-camphor. Chiral polymers poly(CP0-co-TDI) (6) and poly(CP0-co-IPDI) (7) were synthesized by the step polymerization of chiral compound CPO (3) with toluene-2,4-diisocyanate (TDI) and isophorone diisocyanate (IPDI). To inves
Synthesis of chiral polymers having camphanediol moieties and their applications on the optical resolution of some racemates
โ Scribed by Jui-Hsiang Liu; Fu-Ren Tsai; Yuh-Chung Lai
- Publisher
- John Wiley and Sons
- Year
- 1995
- Tongue
- English
- Weight
- 511 KB
- Volume
- 58
- Category
- Article
- ISSN
- 0021-8995
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
To investigate the stereo coordination effect on the optical resolution, chiral monomer (ฯฉ)-5-oxobornyl methacrylate (OBMA) was synthesized and then polymerized under various conditions. In this work, optical resolution was carried out in the presence of chiral polymers having (ฯฉ)-5-oxobornyl moieti
Optically active 2-endo-actoxy-5-endo-bornyl methacrylate ( ABMA) was prepared from (+) -camphor. The homopolymerization of ABMA and copolymerization of ABMA with achiral methyl methacrylate (MMA) or styrene (St) were carried out with 2,2'-azobisisobutyronitrile (AIBN) in benzene. Effects of tempera