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Synthesis of Chiral Nitroxides and an Unusual Racemization Reaction

✍ Scribed by Rychnovsky, Scott D.; Beauchamp, Thomas; Vaidyanathan, Rajappa; Kwan, Tricia


Book ID
120445684
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
178 KB
Volume
63
Category
Article
ISSN
0022-3263

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## Abstract A synthetic route to a series of homochiral (and achiral) nitronyl nitroxides derived from __rac__‐(and __meso__)‐3,4‐dimethyl‐3,4‐dinitrohexane is described. The two forms of this precursor, __meso__ and __rac__, were identified unambiguously and reduced to the corresponding __meso__‐