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Synthesis of Chiral Imino- and Amino-imidazolium Salts and of Chelating Amino-N-heterocyclic Carbene Palladium(II) Complexes.

✍ Scribed by Alexandre Flahaut; Jean-Pierre Baltaze; Sylvain Roland; Pierre Mangeney

Publisher: John Wiley and Sons
Year: 2006
Weight: 14 KB
Volume: 37
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200648108

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## Abstract Methyl 12‐chloromethyl‐dehydroabie‐tate reacts with 1‐benzyl‐ and 1‐arylimidazoles to give unsymmetrically substituted imidazolium chlorides (**1a–i**), with abietane moiety. Starting from methyl 12‐aminodehydroabietate, symmetrically substituted diterpene‐based salts of imidazolinium (