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Synthesis of chiral disubstituted 18-crown-6-ethers with C2symmetry from D-sorbitol

✍ Scribed by É. P. Serebryakov; R. I. Abylgaziev; E. A. Él'perina; M. I. Struchkova


Book ID
112544368
Publisher
Springer
Year
1986
Tongue
English
Weight
47 KB
Volume
35
Category
Article
ISSN
1573-9171

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## Abstract An example of the synthesis of substituted crown‐ethers by radical addition reaction of 18‐crown‐6 (1) to several α‐olefins (2a‐e), cyclohexene (2f), vinyl butyl ether (2g), allyl alcohol (2h), trimethylvinylsilane (2i), diethylmaleate (2j) and formaldehyde (2k) in the presence of a per