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Synthesis of chiral bis-homoallylic epoxides. A new class of lepidopteran sex attractants

โœ Scribed by Millar, Jocelyn G.; Underhill, Edward W.

Book ID
120528776
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
460 KB
Volume
51
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES

Bi(OTf)3-catalyzed allylation of epoxide
Bi(OTf)3-catalyzed allylation of epoxides: a facile synthesis of homoallylic alcohols
โœ J.S. Yadav; B.V.S. Reddy; G. Satheesh ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 168 KB

Epoxides react smoothly with tetraallyltin in the presence of 2 mol% of Bi(OTf) 3 under mild reaction conditions to afford the corresponding homoallylic alcohols in excellent yields with high regioselectivity while aryl aziridines produce exclusively allyl amines in good yields under similar conditi