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Synthesis of chiral, amphiphilic, and water-soluble macrocycles via urea formation

โœ Scribed by Tapes Bhattacharyya; Anders Sundin; Ulf J Nilsson


Book ID
108282350
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
281 KB
Volume
59
Category
Article
ISSN
0040-4020

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An efficient and convergent route toward
โœ Tapes Bhattacharyya; Ulf J Nilsson ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 58 KB

A practical procedure for the synthesis of water-soluble, chiral and amphiphilic macrocyclic molecules is described. Acylation of p-xylylene diamine with Fmoc-protected glycine and aspartic acid, followed by removal of the Fmoc moiety afforded amino acid:p-xylene conjugates as free diamines. These d