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Synthesis of carboranes containing nucleoside bases

โœ Scribed by Yoshinori Yamamoto; Toshiya Seko; Hiroyuki Nakamura; Hisao Nemoto

Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
512 KB
Volume
3
Category
Article
ISSN
1042-7163

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โœฆ Synopsis

Abstract

The carboranes containing uridine derivatives (9a,b,c), and purine base (8) were prepared by the reaction of decaborane with the corresponding acetylene precursors (3a, 3b, 2c and 5b, respectively).

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Numbering according to [la]. For convenience, only one tautomeric form is drawn. ## ' ) The catalyst in these substitution reactions could also be replaced by Pd/C (10%) [9]. In this way, 7-10 were obtained in 5&70% yield.