Synthesis of Carbonates and Related Compounds from Carbon Dioxide via Methanesulfonyl Carbonates
โ Scribed by Bratt, Mark O.; Taylor, Paul C.
- Book ID
- 120159917
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 106 KB
- Volume
- 68
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Table 1. Iy5Pt-NMR data for some platinum-tin complexes [a]. 1runs-[PtC1(SnC1~)(PEt~)~] [c] 28954 -4780 -864 Irun~-[Pt(SnCl~)~(PEt,)~] [d] 20410 -5152 -618 [el trans-[PtH(SnCla)(PEt,)2J [fl 9 067 -5302 -426 truns-[PtH(SnCb)(PPh2CH2Ph)2] [fl 10955 -5322 -428 I~u~~-[P~(C(CO,E~)==CHCOZE~)(S~C~~)(PP~~)
The turnover number of the catalytic production of dimethyl carbonate from CO 2 and methanol is restricted by thermodynamics as well as catalyst decomposition. The catalytic efficiency is remarkably improved using an acetal as the starting material in methanol. The catalytic activity and selectivity