✦ LIBER ✦

Synthesis of C-7 oxidized abietane diterpenes from racemic ferruginyl methyl ether

✍ Scribed by Anpai Li; Xuegong She; Jiyong Zhang; Tongxing Wu; Xinfu Pan

Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 159 KB
Volume: 59
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(03)00883-4

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✦ Synopsis

A series of naturally occurring C-7 oxidized abietane diterpenes have been synthesized from racemic ferruginyl methyl ether in high yields. 6-Hydroxyl-5,6-dehydrosugiol ( 7) can be converted into stable xanthoperol (12) using high temperature. Among the products, the structures of sugiyl methyl ether (2) and 6(-hydroxysugiyl methyl ether (8) were determined by X-ray analysis.

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