## Abstract Deuterium labeled forms of 5α‐androst‐16‐en‐3‐one, 3α‐hydroxy‐5α‐androst‐16‐ene, 3β‐hydroxy‐5α‐androst‐16‐ene, 3β‐hydroxy‐5, 16‐androstadiene and 4, 16‐androstadien‐3‐one were prepared to serve as internal standards in quantitative analysis of C~19~‐Δ^16^ steroids by mass spectrometric
Synthesis of C-19 deuterium labelled steroids
✍ Scribed by Robert L. Dyer; Terry A. Harrow
- Book ID
- 118978637
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 465 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0039-128X
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## Abstract Synthesis of C~19~ steroid monosulphates labelled with deuterium is reported. Deuterium was introduced either at hydroxylated carbons or in methylene groups, in order to permit use of the steroids in studies of intermolecular hydrogen transfer __in vivo__. Methylene groups were deuterat
## Abstract Hexenols are important flavour components of fruit and vegetables. We report the synthesis of __cis__‐3‐hexen‐1‐ol‐6,6,6‐^2^H~3~, hexen‐1‐ol‐6,6,6‐^2^H~3~, hexan‐1‐ol‐6,6,6‐^2^H~3~, __cis__–2‐hexen‐1‐ol‐6,6,6‐^2^H~3~ and __trans__‐2‐hexen‐1‐ol‐6,6,6‐^2^H~3~.