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Synthesis of bridging electron transfer donor ligands

✍ Scribed by Sandrine Chodorowski-Kimmes; Thomas J. Meyer


Book ID
104257081
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
171 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis


The syntheses of three bridging electron transfer donor ligands are described based on coupling of the electron transfer donor, N, N'-dimethylbenzidine with two 2,2'-bipyridines. Two different coupling strategies are used : coupling between an acid and an amine with formation of an amide, and nucleophilic coupling between an amine and an electrophilic bipyridine,


πŸ“œ SIMILAR VOLUMES


ChemInform Abstract: Synthesis of Bridgi
✍ S. CHODOROWSKI-KIMMES; T. J. MEYER πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 26 KB πŸ‘ 1 views

## Synthesis of Bridging Electron Transfer Donor Ligands. -A family of polypyridyl bridging ligands (I) with a gradient of redox potentials (0.54-1.54 V) is synthesized by either coupling between an acid and an amine with formation of an amide or nucleophilic coupling between an amine and an elect