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Synthesis of bridged soluble phthalocyaninatoruthenium complexes

✍ Scribed by Hanack, Michael; Hees, Michael; Elisabeth Witke, and

Book ID
120923274
Publisher
Royal Society of Chemistry
Year
1998
Tongue
English
Weight
183 KB
Volume
22
Category
Article
ISSN
1144-0546

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Tetrakis(trimethysilyl)phthalocyaninatoruthenium(II) (5) has been synthesized via the biaxially coordinated ((CH 3 ) 3 Si) 4 PcRu(3-Clpy) 2 (2) complex by thermal decomposition of the axial ligands of 2. ((CH 3 ) 3 Si) 4 PcRu (5) was characterized by NMR, IR and UV-vis spectroscopy and elemental ana