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Synthesis of Branched Polystyrene and Poly(styrene- b -4-methoxystyrene) by Nitroxyl Stable Radical Controlled Polymerization

✍ Scribed by Tao, Yuefei; He, Junpo; Wang, Zhongmin; Pan, Jingyun; Jiang, Hongjin; Chen, Shimin; Yang, Yuliang

Book ID: 121696266
Publisher: American Chemical Society
Year: 2001
Tongue: English
Weight: 103 KB
Volume: 34
Category: Article
ISSN: 0024-9297
DOI: 10.1021/ma0100201

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## Abstract Radical polymerization of styrene and mixtures of styrene and 4‐vinylpyridine was performed in the presence of 2,2,6,6‐tetramethylpiperidine‐__N__‐oxyl (TEMPO) producing polymers with controlled molecular weights and molecular weight distributions. The living nature of these polymers wa