๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Synthesis of both enantiomers of hiburipyranone

โœ Scribed by Kanako Uchida; Hidenori Watanabe; Takeshi Kitahara

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
637 KB
Volume
54
Category
Article
ISSN
0040-4020

No coin nor oath required. For personal study only.

โœฆ Synopsis

Both enentiomersofhiburipyranone, acytotoxic metabolite o~marines~nge, ~~synt~sized employing Sharpless' asymmetric ~h~~oxy~at~o~ as a key step and absolute con~~~mt~o~ of the natural compound at C-3 position was dete~in~ to be R.

๐Ÿ“œ SIMILAR VOLUMES

Synthesis of both enantiomers of halitun
Synthesis of both enantiomers of halitunal
โœ Kazunori Shimano; Yuting Ge; Kazuhiko Sakaguchi; Sachihiko Isoe ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 216 KB
Chemoenzymatic synthesis of both enantio
Chemoenzymatic synthesis of both enantiomers of cispentacin
โœ Fritz Theil; Sibylle Ballschuh ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 465 KB

Based on the lipase-catalysed kinetic resolution of the silyloxyalcohol (1RS,2SR)-5 by transesterification with vinyl acetate in the presence of lipase from Pseudomonas cepacia a synthesis of both enantiomers of the ~-amino acid cispentacin (1R,2S)-I and (1S,2R)-I using simple functional group inter