𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of (Boryl)(silyl)iminomethanes by Insertion of Isonitriles into Silicon−Boron Bonds

✍ Scribed by Suginome, Michinori; Fukuda, Takeshi; Nakamura, Hiroshi; Ito, Yoshihiko


Book ID
121228405
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
109 KB
Volume
19
Category
Article
ISSN
0276-7333

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Versatile Conversion of N-Heterocyclic S
✍ Dr. Yun Xiong; Dr. Shenglai Yao; Prof. Dr. Matthias Driess 📂 Article 📅 2012 🏛 John Wiley and Sons 🌐 English ⚖ 270 KB

The facile one-pot reaction of the stable N-heterocyclic silylene LSi: 1 (L=(ArN)C(=CH(2))CH=C(Me)(NAr), Ar=2,6-iPr(2)C(6)H(3)) with Me(2)Zn, Me(3)Al, H(3)Al-NMe(3), and MeLi has been investigated. The silicon(II) atom in 1 is capable of insertion into the corresponding M-C and Al-H bonds under very