The homopolymerization of methyl methacrylate (MMA) in the presence of 2,2,6,6-tetramethyl-l-piperidinyloxy (TEMPO) is described and compared to the TEMPO-mediated polymerization of styrene. Furthermore, the formation of block copolymers between MMA and styrene from polystyrene chains with TEMPO fra
Synthesis of Block Copolymers Possessing Fluoropolymer and Non-Fluoropolymer Segments by Radical Polymerization
✍ Scribed by Shi, Zhiqing; Holdcroft, Steven
- Book ID
- 120410108
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 255 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0024-9297
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## Abstract A series of polystyrene‐__block__‐poly(__n__‐butyl methacrylate) (PS‐__b__‐P__n__BMA) diblock copolymers (di‐BCPs) with an azobenzene moiety [__trans__‐4‐methacryloyloxyazobenzene (MOAB)] in the P__n__BMA segment was prepared by atom transfer radical polymerization (ATRP). P(__n__BMA‐__
End-functional polystyrenes with an N,N-diethyldithiocarbamyl group were prepared by the photopolymerization of styrene with novel diethyldithiocarbamate derivatives as photoiniferters. Under ultraviolet light, the end-functional polymers could initiate a second monomer to polymerize and form block