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Synthesis of block copolymers based on poly(p-benzamide) with a polyamide benzimidazole

โœ Scribed by Giuseppina Conio; Aldo Tealdi; Enrico Marsano; Alberto Mariani; Igor Ponomarev


Book ID
107847164
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
236 KB
Volume
35
Category
Article
ISSN
0032-3861

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Copolymers were prepared by the condensation of rigid benzoyl-terminated poly@-benzamide) and flexible anilino-terminated poly(m-benzamide) prepolymers. The use of two monomers of the AB type and of end-capped prepolymers resulted in the formation of diblock molecules uncontaminated by triblock or m

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## Abstract Anilinoโ€terminated poly(__m__โ€phenylene isophthalamide) [PhNH(MPDโ€I)] and benzoyl terminated poly(__p__โ€benzamide) [PhCO(PBA)] were coupled according to a oneโ€pot twoโ€step scheme of Yamazaki's reaction. Diblock copolymers with varying length of the flexible PhNH(MPDโ€I) segment, and simi