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Synthesis of Bis(chlorodisulfanyl)benzenes and Hexathia[3.3]cyclophanes

✍ Scribed by Prof. Dr. Franz Fehér; Dr. Klaus Glinka; Dipl.-Chem. Franz Malcharek


Publisher
John Wiley and Sons
Year
1971
Tongue
English
Weight
231 KB
Volume
10
Category
Article
ISSN
0044-8249

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Multibridged [3n]Cyclophanes, 1. Synthes
✍ Shinmyozu, Teruo ;Kusumoto, Shirou ;Nomura, Sachiyo ;Kawase, Haruo ;Inazu, Takah 📂 Article 📅 1993 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 453 KB 👁 2 views

The acid-catalyzed cyclization of a pseudogeminally substituted acetyl group and a chloromethyl group of tri-bridged cyclophane 7 , followed by reduction of the carbonyl group afforded (3,](1,2,3,5)cyclophane 3. One-step TosMIC coupling reaction of tetrabromide 12 and subsequent reduction of the car