Skeletal rearrangement via alkoxy radica
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Atsushi Nishida; You-Ichirou Kakimoto; Yukie Ogasawara; Norio Kawahara; Mayumi N
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Article
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1997
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Elsevier Science
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French
โ 171 KB
The radical reaction of three epoxydecalin thiocarbonylimidazolides was investigated using nBu3SnH and AIBN. Two types of rearrangement from a tenmembered cyclic carbon radical, which was formed by 13-cleavage of alkoxy radicals, were observed.